Surface Modifications of Superparamagnetic Iron Oxide Nanoparticles with Polyvinyl Alcohol and Graphite as Methylene Blue Adsorbents
نویسندگان
چکیده
Methylene blue (MB) is one of the toxic synthetic dyes that are being discharged heavily into water supplies. Hence, MB removal most important tasks for a cleaner supply. By using inexpensive, abundant, and easy-to-synthesize materials, superparamagnetic iron oxide nanoparticles, which were synthesized co-precipitation method with polyvinyl alcohol graphite (SPION/PVA/GR), can be used to adsorb MB. The adsorbent was characterized FE-SEM, FTIR, XRD, VSM, BJH. entrapment efficiency on SPION/PVA/GR after 12 days 33.96 ± 0.37–42.55 0.39%, at 333.15, 310.15, 298.15 K, initial concentration 0.017–0.020 mg/mL. adsorption process considered spontaneous, endothermic, chemisorption, heterogeneous, or multilayer adsorption. When releasing K pH 3.85 7 days, release percentage ranged from 11.56 0.33 22.93 5.06 depending loading conditions mainly temperature following Higuchi kinetic model. Since this novel SPION-based adsorbent, optimization, different forms (i.e., thin film composite) should further researched.
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ژورنال
عنوان ژورنال: Coatings
سال: 2023
ISSN: ['2079-6412']
DOI: https://doi.org/10.3390/coatings13091558